Product ID:PIC REAGENT B-5, 85110
MSDS Date:11/16/1994
FSC:6630
NIIN:00N072646
MSDS Number: CDPRH

WATERS CORP

34 MAPLE ST
MILFORD, MA 01757
US

Emergency Phone: 615-366-2000

Info Phone: 508-478-2000

Cage: 00W06

WATERS CORP

MILFORD, MA 01757 US

Telephone: 508-478-2000

Cage: 00W06

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 25%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-PENTANESULFONIC ACID, SODIUM SALT

CAS: 22767-49-3

Fraction By Weight: 20-25%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: N/K

INVOLVED IN FIRE. EXTING ONLY IF FLOW CAN BE

RTECS: 9999999ZZ

BE INEFT. COOL CNTNRS W/FLOODING AMTS OF WATER FROM

RTECS: 9999999ZZ

CORNEA. DILUTE SOLNS-MILD IRRIT; UNDILUTED

RTECS: 9999999ZZ

IRRIT & MOD

RTECS: 9999999ZZ

MILD & TRANSIENT IRRIT &

RTECS: 9999999ZZ

FOLLOWING DELAY, COUGH, DYSP, HDCH, DULL, WEAK,

RTECS: 9999999ZZ

PAIN IN BACK, ABDOMEN, EXTREMS, RESTLESSNESS,

RTECS: 9999999ZZ

TO METABOLIC ACIDOSIS, COLD & CLAMMY SKIN,

RTECS: 9999999ZZ

CARD DEPRESS, PERIPHERAL NEURITIS, CEREBRAL/PULM

RTECS: 9999999ZZ

DIMMED VISION, DILATED, UNRESPONSIVE PUPILS, PTOSIS,

RTECS: 9999999ZZ

DIPLOPIA, CHANGE IN COLOR PERCEPTION, PHOTOPHOBIA &

RTECS: 9999999ZZ

TRANSIENT/PERM BLINDNESS. BILATERAL SENSORINEURAL

RTECS: 9999999ZZ

PANCREATIC DMG. DEATH DUE TO RESP

RTECS: 9999999ZZ

PRLNG ASTHENIA/IRREVERSIBLE EFTS ON NERV SYS INCL

RTECS: 9999999ZZ

GI IRRIT, DIZZ, NAUS, VOMIT.

RTECS: 9999999ZZ

EFTS AS IN ACUTE

RTECS: 9999999ZZ

8000 PPM-MARKED DIMINUTION OF VISION & ENLARGEMENT

RTECS: 9999999ZZ

DEFAT RSLTG IN ERYTHEMA, SCALING &

RTECS: 9999999ZZ

CONJ.

RTECS: 9999999ZZ

IN ACUTE INGEST. REPRO EFTS-ANIMALS. TARGET

RTECS: 9999999ZZ

NO SMOKING, FLAMES/FLARES IN HAZ AREA! KEEP

RTECS: 9999999ZZ

IS REPORTABLE UNDER CERCLA, NRC MUST BE NOTIFIES

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRIT/NARC/NEUROTOX. ACUTE:INHAL:ING
1:IRRIT OF MUC MEMBS, COUGH, OPPRESSION IN CHEST, TRACHEITIS,
BRONCH, TINNITIS, UNSTEADY GAIT, TWITCHING, COLIC, CONSTIP,
NYSTAGMUS & BLEPHAROSPASM. PARESTHESIAS, NUMB & SHOOTING PAINS IN
HANDS & FOREARMS, METABOLIC ACIDOSIS & EFTS ON EYES & CNS AS
DETAILED IN ACUTE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGEST. ING 2:IRRIT. SKIN:ING 1:IRRIT.
ABSORP MAY OCCUR (METABOLIC ACIDOSIS & EFTS ON EYES & CNS AS
DETAILED IN ACUTE INGEST. ING 2:IRRIT. ERYTHEMA, SORENESS & PAPULAR
DERM. THICKENING OF SKI N W/WEEPING, CRACKING, SCALING/BLISTERING.
EYE:ING 1:IRRIT. VIOLENT INFLAMM OF CONJ & EPITHELIAL DEFECTS ON
(ING 6)
Medical Cond Aggravated by Exposure:PERSONS W/KIDNEY, EYE OR SKIN
DISORDERS ARE AT INCREASED RISK FROM EXPOSURE.

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . FOR MORE
SPECIFIC INFORMATION REGARDING FIRST AID TREATMENT CONTACT NEHC .

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY/ALCOHOL-RESIST FOAM. FOR LGR FIRES, USE WATER SPRAY,
FOG/ALCOHOL-RESIST FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. MOVE
CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. DIKE FIRE-CTL
WATER FOR LATER DISP; DO NOT SCATTER(SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOS TO
HEAT/FLAME. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO
SOURCE OF IGNIT & FLASH BACK. VAP-AIR MIXTURES ARE EXPLOSIVE.

Spill Release Procedures:SHUT OFF IGNIT SOURCES. DO NOT TOUCH SPILLED
MATL. STOP LEAK IF YOU CAN DO IT W/OUT RISK. USE WATER SPRAY TO
REDUCE VAPS. SM SPILLS:TAKE UP W/SAND/OTHER ABSORB MATL & PLACE
INTO CNTNRS FOR LATER DISP. LG SPILLS:DIKE FAR AHEAD FOR LATER
DISP. (ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
STORING SUBSTANCE. STORE I/A/W 29CFR 1910.106. STORE AWAY FROM
INCOMPAT SUBSTANCES. MAY BE IRRIT TO RESP TRACT.
Other Precautions:FLAMM LIQ & VAP. MAY CAUSE FLASH FIRE. KEEP AWAY FROM
ALL IGNIT SOURCES. AVOID BRTHG VAP/MIST. AVOID CONT W/EYES, SKIN &
CLTHG. KEEP CNTNR TIGHTLY CLSD. USE ONLY W/ADEQ VENT. HANDLE
W/CAUT. FOR MORE S PECIFIC INFO, CONTACT NEHC .

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHST VENT TO MEET PELS. VENT EQUIP SHOULD BE
EXPLO-PROOF IF EXPLO CONCS OF DUST, VAPOR/FUME ARE PRESENT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING &
EQUIPMENT.
Work Hygienic Practices:WASH THORO AFTER HNDLG. ANY CLTHG WET W/FLAMM
LIQ SHOULD BE IMMED REMOVED AT LOCATION WHERE IT IS WETTED TO PVNT
IGNIT.
Supplemental Safety and Health
FIRE FIGHT PROC:MATL. APPLY COOLING WATER TO SIDES OF CNTNRS EXPOS TO
FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS.
W/DRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY DEVICE/A NY
DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1/2 MILE IN ALL
DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK IS (ING 4)

Vapor Pres:24 @ 25C
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, METALS, CHLORINE, LEAD & SULFURIC ACID. FOR
COMPLETE LIST OF MATLS TO AVOID CONT NEHC .
Stability Condition to Avoid:NO DATA AVAILABLE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC &/OR HAZARDOUS GASES.

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE. DISPOSAL MUST BE I/A/W STANDARDS
APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA
HAZARDOUS WASTE #D001. RQ :100 LBS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.